Review of world experience and properties of materials for encapsulation of terrestrial photovoltaic arrays

Published and unpublished information relating to encapsulation systems and materials properties was collected by searching the literature and appropriate data bases (over 1,300 documents were selected and reviewed) and by personal contacts including site and company visits. A data tabulation summarizing world experience with terrestrial photovoltaic arrays (50 installations) is presented in the report. Based on criteria of properties, processability, availability, and cost, candidate materials were identified which have potential for use in encapsulation systems for arrays with a lifetime of over 20 years high reliability, an efficiency greater than 10 percent, a total price less than $500/kW, and a production capacity of 500,000 kW/yr. The recommended materials (all commercially available) include, depending upon the device design, various borosilicate and soda-lime glasses and numerous polymerics suitable for specific encapsulation system functions

Evaluation of selected chemical processes for production of low-cost silicon

Plant construction costs and manufacturing costs were estimated for the production of solar-grade silicon by the reduction of silicon tetrachloride in a fluidized bed of seed particles, and several modifications of the iodide process using either thermal decomposition on heated filaments (rods) or hydrogen reduction in a fluidized bed of seed particles. Energy consumption data for the zinc reduction process and each of the iodide process options are given and all appear to be acceptable from the standpoint of energy pay back. Information is presented on the experimental zinc reduction of SiCl4 and electrolytic recovery of zinc from ZnCl2. All of the experimental work performed thus far has supported the initial assumption as to technical feasibility of producing semiconductor silicon by the zinc reduction or iodide processes proposed. The results of a more thorough thermodynamic evaluation of the iodination of silicon oxide/carbon mixtures are presented which explain apparent inconsistencies in an earlier cursory examination of the system

Evaluation of selected chemical processes for production of low-cost silicon, phase 2

Potential designs for an integrated fluidized-bed reactor/zinc vaporizer/SiCl4 preheater unit are being considered and heat-transfer calculations have been initiated on versions of the zinc vaporizer section. Estimates of the cost of the silicon prepared in the experimental facility have been made for projected capacities of 25, 50, 75, and 100 metric ton of silicon. A 35 percent saving is obtained in going from 25 metric ton/year to the 50 metric ton/year level. This analysis, coupled with the recognition that use of two reactors in the 50 metric ton/year version allows for continued operation (at reduced capacity) with one reactor shut down, has resulted in a recommendation for adoption of an experimental facility capacity of 50 metric ton/year or greater. At this stage, the change to a larger size facility would not increase the design costs appreciably. In the experimental support program, the effects of seed bed particle size and depth were studied, and operation of the miniplant with a new zinc vaporizer was initiated, revealing the need for modification of the latter

Collective spin systems in dispersive optical cavity QED: Quantum phase transitions and entanglement

We propose a cavity QED setup which implements a dissipative Lipkin-Meshkov-Glick model -- an interacting collective spin system. By varying the external model parameters the system can be made to undergo both first-and second-order quantum phase transitions, which are signified by dramatic changes in cavity output field properties, such as the probe laser transmission spectrum. The steady-state entanglement between pairs of atoms is shown to peak at the critical points and can be experimentally determined by suitable measurements on the cavity output field. The entanglement dynamics also exhibits pronounced variations in the vicinities of the phase transitions.Comment: 19 pages, 18 figures, shortened versio

Characterizing Quantum Microwave Radiation and its Entanglement with Superconducting Qubits using Linear Detectors

Recent progress in the development of superconducting circuits has enabled the realization of interesting sources of nonclassical radiation at microwave frequencies. Here, we discuss field quadrature detection schemes for the experimental characterization of itinerant microwave photon fields and their entanglement correlations with stationary qubits. In particular, we present joint state tomography methods of a radiation field mode and a two-level system. Including the case of finite quantum detection efficiency, we relate measured photon field statistics to generalized quasi-probability distributions and statistical moments for one-channel and two-channel detection. We also present maximum-likelihood methods to reconstruct density matrices from measured field quadrature histograms. Our theoretical investigations are supported by the presentation of experimental data, for which microwave quantum fields beyond the single-photon and Gaussian level have been prepared and reconstructed.Comment: 14 pages, 5 figure

Analyzing large-scale conservation interventions with Bayesian hierarchical models: a case study of supplementing threatened Pacific salmon.

Myriad human activities increasingly threaten the existence of many species. A variety of conservation interventions such as habitat restoration, protected areas, and captive breeding have been used to prevent extinctions. Evaluating the effectiveness of these interventions requires appropriate statistical methods, given the quantity and quality of available data. Historically, analysis of variance has been used with some form of predetermined before-after control-impact design to estimate the effects of large-scale experiments or conservation interventions. However, ad hoc retrospective study designs or the presence of random effects at multiple scales may preclude the use of these tools. We evaluated the effects of a large-scale supplementation program on the density of adult Chinook salmon Oncorhynchus tshawytscha from the Snake River basin in the northwestern United States currently listed under the U.S. Endangered Species Act. We analyzed 43 years of data from 22 populations, accounting for random effects across time and space using a form of Bayesian hierarchical time-series model common in analyses of financial markets. We found that varying degrees of supplementation over a period of 25 years increased the density of natural-origin adults, on average, by 0-8% relative to nonsupplementation years. Thirty-nine of the 43 year effects were at least two times larger in magnitude than the mean supplementation effect, suggesting common environmental variables play a more important role in driving interannual variability in adult density. Additional residual variation in density varied considerably across the region, but there was no systematic difference between supplemented and reference populations. Our results demonstrate the power of hierarchical Bayesian models to detect the diffuse effects of management interventions and to quantitatively describe the variability of intervention success. Nevertheless, our study could not address whether ecological factors (e.g., competition) were more important than genetic considerations (e.g., inbreeding depression) in determining the response to supplementation

A quantum evaporation effect

A small momentum transfer to a particle interacting with a steep potential barrier gives rise to a quantum evaporation effect which increases the transmission appreciably. This effect results from the unexpectedly large population of quantum states with energies above the height of the barrier. Its characteristic properties are studied and an example of physical system in which it may be observed is given.Comment: 7 pages + 3 figure

Reservoir engineering and dynamical phase transitions in optomechanical arrays

We study the driven-dissipative dynamics of photons interacting with an array of micromechanical membranes in an optical cavity. Periodic membrane driving and phonon creation result in an effective photon-number conserving non-unitary dynamics, which features a steady state with long-range photonic coherence. If the leakage of photons out of the cavity is counteracted by incoherent driving of the photonic modes, we show that the system undergoes a dynamical phase transition to the state with long-range coherence. A minimal system, composed of two micromechanical membranes in a cavity, is studied in detail, and it is shown to be a realistic setup where the key processes of the driven-dissipative dynamics can be seen.Comment: 16 pages, 9 figure

Spatial fluctuations in an optical parametric oscillator below threshold with an intracavity photonic crystal

We show how to control spatial quantum correlations in a multimode degenerate optical parametric oscillator type I below threshold by introducing a spatially inhomogeneous medium, such as a photonic crystal, in the plane perpendicular to light propagation. We obtain the analytical expressions for all the correlations in terms of the relevant parameters of the problem and study the number of photons, entanglement, squeezing, and twin beams. Considering different regimes and configurations we show the possibility to tune the instability thresholds as well as the quantumness of correlations by breaking the translational invariance of the system through a photonic crystal modulation.Comment: 12 pages, 7 figure

Methodology for designing accelerated aging tests for predicting life of photovoltaic arrays

A methodology for designing aging tests in which life prediction was paramount was developed. The methodology builds upon experience with regard to aging behavior in those material classes which are expected to be utilized as encapsulant elements, viz., glasses and polymers, and upon experience with the design of aging tests. The experiences were reviewed, and results are discussed in detail